Greg, the twin wall Polycarbonate panels that I have on my greenhouse are Teflon coated on one side. The coated side is placed toward the sun to prevent any degradation or yellowing. I have had PC glazing on my greenhouse for some years and, so far at least, I have seen no yellowing. Now that I read your post, I will keep an eye and see if I notice ay coloring.
I don't know much about polymethyl methacrylate. Does it allow more or less, or the same amount of light to pass into the greenhouse as polycarbonate? - Millet