That's Peach Leaf Curl. It's a fungus. Spraying now will not do anything. You need to apply when the tree is dormant or when it first starts to push new buds in the spring, maybe twice then depending on weather conditions.
Or you can just deal with it- it shouldn't kill the tree but will affect growth and fruit production.
See link for more information-
http://www.ipm.ucdavis.edu/PMG/PESTNOTES/pn7426.html